Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes.

نویسندگان

  • Christine M Thomas
  • J Wesley Napoline
  • Gerard T Rowe
  • Bruce M Foxman
چکیده

The reactivity of heterobimetallic Zr/Co complexes linked by phosphinoamide ligands towards the oxidative addition of I(2) and alkyl halides is reported. These reactions are accompanied by dissociation of one phosphine ligand from Co and eta(2)-coordination to Zr. Addition of H(2) leads to both oxidative addition across the M-M bond and P-N bond cleavage.

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عنوان ژورنال:
  • Chemical communications

دوره 46 31  شماره 

صفحات  -

تاریخ انتشار 2010